Svalbard: projects/activities

The IPY-project ‘COPOL’ has a main objective of understanding the dynamic range of man-made contaminants in marine ecosystems of polar regions, in order to better predict how possible future climate change will be reflected in levels and effects at higher trophic levels. This aim will be addressed by 4 integrated work packages covering the scopes of 1) food web contaminant exposure and flux, 2) transfer to higher trophic levels and potential effects, 3) chemical analyses and screening, 4) synthesis and integration. To study the relations between climate and environmental contaminants within a project period of four years, a “location-substitutes-time”-approach will be employed. The sampling is focussed towards specific areas in the Arctic, representing different climatic conditions. Two areas that are influenced differently by different water masses are chosen; the Kongsfjord on the West-coast of Spitzbergen (79N, 12 E) and the Rijpfjord North-East of Svalbard (80N, 22 E). The main effort is concentrated in the Kongsfjord. This fjord has been identified as particularly suitable as a study site of contaminants processes, due to the remoteness of sources, and for influences of climatic changes, due to the documented relation between Atlantic water influx and the climatic index North Atlantic Oscillation (NAO). The water masses of the Rijpfjord have Arctic origin and serves as a strictly Arctic reference. Variable Atlantic water influx will not only influence abiotic contaminant exposure, but also food web structure, food quality and energy pathways, as different water masses carry different phyto- and zooplankton assemblages. This may affect the flux of contaminants through the food web to high trophic level predators such as seabirds and seals, due to altered food quality and energy pathways.

The project aims at establishing a long-term Arctic-Antarctic network of monitoring stations for atmospheric monitoring of anthropogenic pollution. Based upon the long and excellent experiences with different scientific groups performing air monitoring within the Arctic Monitoring and Assessment Programme (AMAP), an expanded network will be established including all AMAP stations and all major Antarctic “year-around” research stations. As an integrated project within the “International Polar Year 2007-08” initiative, the ATMOPOL co-operation intend to • Establish a long-term coordinated international Arctic-Antarctic contaminant programme. • Develop and implement a joint sampling and monitoring strategy as an official guideline for all participating stations. • Support bi-polar international atmospheric research with high-quality data on atmospheric long-range transport of contaminants (sources, pathways and fate). • Support future risk assessment of contaminants for Polar Regions based on effects of relevant contamination levels and polar organisms Based upon the well-established experiences of circum-Arctic atmospheric contaminant monitoring in the Arctic under the AMAP umbrella, a bi-polar atmospheric contaminant network will be established and maintained. In conjunction with the polar network of atmospheric monitoring stations for air pollution, surface-based and satellite instrumentation will be utilised to provide the characterization of the Arctic atmospheric-water-ice cycle. Together with numerical weather prediction and chemical transport model calculations, simultaneous measurements of pollutants at various locations in the Arctic and Antarctic will enhance our understanding of chemical transport and distribution as well as their long-term atmospheric trends. In addition to investigating the importance of atmospheric transport of pollutants an understanding of the transference and impact of these pollutants on both terrestrial and marine environments will be sought. A secretariat and a “scientific project board” will be established. During this initial phase of the project (2006), a guideline on priority target compounds, sampling strategies, equipment and instrumentation, analytical requirements, as well as quality assurance protocols (including laboratory intercalibration exercises) will be developed and implemented. The ATMOPOL initiative aims to address highly relevant environmental change processes and, thus, will strive to answering the following scientific questions: • How does climate change influence the atmospheric long-range transport of pollutants? • Are environmental scientists able to fill the gaps in international pollution inventories and identification of possible sources for atmospheric pollution in Polar Regions? • What are the differences in transport pathways and distribution patterns of various atmospheric pollutants between Arctic and Antarctic environments? Why are there such differences? What is the final fate of atmospherically transported pollutants and how does this impact on the environment and indigenous people?In order to understand the underlying atmospheric chemistry of pollution, e.g. atmospheric mercury deposition events, routine surface measurements of UV radiation as well as campaign related measurements of UV radiation profiles will also be included.The project will establish a cooperative network on atmospheric contaminant monitoring in Polar Regions far beyond the IPY 2007/08 period and is, thus, planned as an “open-end” programme. All produced data will be available for all participating institutions for scientific purposes as basis for joint publications and reports from the ATMOPOL database to be developed.

Marine foodwebs as vector and possibly source of viruses and bacteria patogenic to humans shall be investigated in a compartive north-south study. Effects of sewage from ships traffic and urban settlements, on animals of arctic foodwebs will be studied.

The 2004-2007 scientific research program CHIMERPOL II consists in improving the results obtained during the CHIMERPOL I programme around three main ideas: 1-Understand physico-chemical processes of oxidation of elemental gaseous mercury in the atmosphere during Mercury Depletion Events (MDE) in Corbel, Svalbard from 2004 to 2007 with a continuous monitoring station for gaseous mercury and its speciation, 2-Evaluate deposition and emission fluxes of mercury above the Arctic snow pack by a continuous monitoring of these fluxes in Corbel, Svalbard and in Station Nord, Greenland, from 2005 to 2007. 3-Determine the Air-Snow-Firn-Ice transfer function for mercury and its speciation with a complete balance of mercury in the different compartments in Summit, Greenland from 2006 to 2007.

This technological program aims to get a better view of the Corbel site quality (78 54 N, 12 07 E, Svalbard close to Ny Alesunsd) for atmospheric chemistry. Nox and SO2 samplers are deployed on 16 places on a 4 km2 area around the Station (79°N, Svalbard), protected from snowscooters activity. The influence of Ny Alesund village is also studied. Programme 2004 April 2004 : poles installation and samplers deployment on the 16 stations; analysis will be made by CNR.

The aims of the project are: - to evaluate the fluxes of radionuclides in the water column and their accumulation in the sediment, on a short-time scale; - to determine the C/N and delta13C-delta15N ratios in suspended and sedimentary matter, and test their use as tracers of origin, composition and transformation pathways of organic particles. The selected study area is the Kongsfjord-Krossfjord system, Svalbard, considered as representative test-site for studying processes occurring in Arctic fjords. The focus of the project will be on the processes occurring at the glacier-sea interface, where enhanced lithogenic and biogenic particle fluxes are reported in summer. Specific methods will be used to trace the particle sources. The rate of accumulation-resuspension processes will also be investigated from the inner fjord to the outer continental shelf.

The major goal of the process study between April 15 and May 15, 2003 is to obtain quantified information on reaction path-ways, products and net deposition of mercury during Arctic sunrise.

To distinguish between atmospheric and marine transport of contaminants to northen latitudes by comparison inventories of lake and fjordic sediments.

The selected study area in Svalbard is consideres a representative test-site for studying processes occurring in Arctic fjords. The focus of the project is on the processes occurring at the glacier-sea interface, where enhanced lithogenic and biogenic particle fluxes are reported in summer.Specific methods are used to trace the particle sources. The rate of accumulation-resuspenion precesses is also investigated from the inner fjord to the outer continental shelf.

Total deposition sampling is performed at Ny-Ålesund to study atmospheric fluxes of heavy metals to the Arctic. In addition wet only deposition sampling is carried out with an automatic precipitation sampler. The samples are analysed at the home laboratory for tracer elements for seaspray components, earthcrust weathered material and anthropogenic elements by atomic absorption spectrometry and inductively coupled plasma-mass spectrometry (ICP-MS). One aim of our study is to distinguish element distribution between the dissolved and particulate phase. In addition to the element analyses the concentration of anions is determined by ionchromatography. In 1996 an automatically operating aerosol sampler was installed, which is combined with the automatic precipitation sampler to study element washout from aerosol particles via rain and snow.

Due to the high organochlorine concentrations reported in Arctic top predators, and the potential transport of contaminants with the drifting sea-ice in the Arctic, organisms constituting lower trophic levels living in association with sea-ice have been proposed as susceptible of uptake of high loads of organic pollutants. The present project studies the organochlorine occurrence in organisms living in the marginal ice zone north of Svalbard and in the Fram Strait. This includes both ice fauna (ice-amphipods), zooplankton, polar cod and different seabird species foraging in the marginal ice zone. Our objectives are to investigate: *The bioaccumulation of organochlorines in ice-associated amphipods in relation to diet preference, spatial variation due to sea ice drift route, size, sampling year, uptake and distribution within the body. *Comparison of organochlorine contamination in pelagic and ice-associated organisms at the similar trophic position, to investigate the effect of sea ice as a transporter and concentrator of pollutants. *Spatial variation in zooplankton species, related to differences in water masses and exposure to first year or multi year sea ice. *The contamination load in different seabirds feeding in the marginal ice zone, in relation to diet choice and estimated trophic position, taxonomically closeness and the induction of hepatic CYP P450 enzymes.

Surface samples collected around Svalbard in 1997 have been analysed for total content of heavy metals, Polycyclic Aromatic Hydrocarbons (PAHs), Polychlorinated Biphenyls (PCBs) and a selection of pesticides. Sample localities have been selected to include areas not covered by previous investigations. Based on the data set and results from previous expeditions in the area, contamination levels as well as potential sources for the pollutants are discussed. The PAH levels for most stations are moderately elevated with a high contribution of aromatic hydrocarbons associated with petrogenic sources. Hence the dominant sources for the PAHs is most likely derived from petroleum seepage and or coal mining. Long-range transport of aromatics associated with anthropogenic input is a minor component of the observed PAH levels. The highest concentration of PAH is found in Storfjorden with a value higher than the elevated concentrations earlier reported from the south-eastern Storfjorden and over the Central Bank. The concentration levels of the metals arsenic, lead, chromium and nickel were moderately elevated. Because of sparse information on the natural geomorphology, background metal concentrations are not known for this area. Hence, no quantitative comparison of natural and anthropogenic inputs for metals can be made. However, the most dominant source is assumed to be natural and related to the geological conditions in the area. All PCB levels were low, suggesting a dominant influence of long-range transport of these compounds to the area. Pesticide data showed low contamination of all compounds and suggests a predominant long-range atmospheric source for these pollutants.

The project aims to carry out an environmental assessment of the marine environment close to the three main settlements in the Isfjorden complex; Barentsburg, Longyearbyen and Pyramiden. The study comprises analyses of sediment geochemistry and soft-bottom benthic fauna. Attention is given to distinguishing atmospheric transport of contaminants from those arising from local sources.

Polybrominated diphenyl ethers (PBDEs) are persistent and lipophilic compounds used as flame retardants in electronic equipment, plastic material and synthetic fibbers among other things. The PBDEs are mainly used as Deca-BDE and Bromokal 70-5DE, a mixture of tetra-, penta- and hexa-BDE. Due to its chemical and physical properties PBDEs, especially TeBDEs, tend to bioaccumulate. PBDEs were first reported in sediments in USA, and in fish from a Swedish river. More recently PBDEs have also been reported in seals, birds, mussels, whales and humans. In this study an SFE-method for rapid analysis of PBDEs in marine mammals was developed. This method was used to determinate the concentrations of these environmental pollutants in Pilot Whale samples caught in the Faroe Islands, Beluga Whales from the Arctic and Polar Bears from Svalbard. Using this method several PBDEs were analysed in the different species. In addition methoxylated PBDEs (Me-O-PBDE) were identified by interpretation of the different mass spectra’s. Of the 209 theoretical possible congeners only a few PBDE seem to accumulate in the environment. Accumulation of PBDE is related to the different chemical properties of the molecule. With the help of multivariate characterisation of a compound class using semi-empirical molecular orbital calculations, literature data and actual experimental measurements, the behaviour of PBDE in the environment can be modelled and predicted. Such models are essential in order to gain more insight in the behaviour of PBDE in the environment.