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The project aims at producing an ENVISAT-1 mission-long monitoring of the inorganic chlorine (Cly) and fluorine (Fy) loading in the Earth’s middle atmosphere, based on FTIR vertical column abundance measurements of the key related species HCl, ClONO2, HF and COF2 at 10 ground-based NDSC sites distributed worldwide. These Cly and Fy inventories will be completed with ClO and OClO measurements expected as Level-2 products from ENVISAT-1. The column abundances of the source gases CFC-12 and HCFC-22 will be used to place the stratospheric Cly and Fy evolution in perspective with the more complete sets of organic chlorinated and fluorinated compounds measured at the ground by the in situ networks NOAA-CMDL and AGAGE. The assimilation of the retrieved geophysical data bases will be performed through 3-D model calculations incorporating physical, chemical and transport characteristics of the global atmosphere.
The present project aims at the geophysical validation, from pole to pole and on the long term, of key ozone-related level-2 products (O3, NO2, BrO, OClO, and ClO) from GOMOS, MIPAS and SCIAMACHY onboard ENVISAT-1, and at a contribution to the maturation of the related level-1b-to-2 data processors. Application data processing will be used to convert level-2 data into a more suitable format for validation and scientific end-users. The respective performances of the ENVISAT data products, and their sensitivity to various relevant parameters, will be investigated from the Arctic to the Antarctic, over a variety of geophysical conditions. The impact of these performances on specific atmospheric chemistry studies will be emphasised. The pseudo-global investigations will rely on correlative studies of ENVISAT data with high-quality ground-based, in situ and balloon observations associated with the Network for the Detection of Stratospheric Change (NDSC).
The project will provide a long-term, pseudo-global validation support to the ENVISAT-1 atmospheric measurements, based on mutually consistent high-quality solar and lunar observations from FTIR spectrometers operated at primary and a number of complementary NDSC stations. The validation is limited to a number of target species, most of which are primary NRT or OL level-2 products of the mission, with focus on NOy components: O3, NO2, NO, N2O, HNO3, HNO4, H2CO, CO and CH4. Synergistic use will be made of column and profile data from MIPAS, GOMOS and SCIAMACHY. The ground network will deliver mean vertical column abundances for all target species with NDSC-type quality, and height profile information for some target gases as secondary products to the PI's home institute, where the correlative analyses with the ENVISAT-1 products will be done. Asynoptic mapping tools will support the validation efforts.
The main objectives of ESAC II are the following: (1) Extend and improve the important existing Belgian contribution in atmospheric research started in the 50s, recognized internationally. (2) Investigate the chemistry of the atmosphere, to detect and understand its evolution, mainly with experimental means. Special attention will be paid to the evolution of the ozone layer and chemical species and processes with an impact on climate changes. (3) Support the Belgian policies and decisions regarding the Amendments to: - the Montreal Protocol on Substances that deplete the Ozone Layer; - the Kyoto Protocol on Greenhouse Gases (GHG) emissions.
SOGE is an integrated system for observation of halogenated greenhouse gases in Europe. There are two objectives: (1) To develop a new cost-effective long-term European observation system for halocarbons. The results will be in support of the Kyoto and the Montreal protocols,in assessing the compliance of European regions with the protocol requirements. In particular the observation system will be set up to: - detect trends in the concentrations of greenhouse active and ozone-destroying halocarbons; - verify reported emissions and validate emission inventories; - develop observational capacity for all halocarbons included in the Kyoto protocol (PFC, SF6) for which this is presently not yet existing; - develop a strategy for a cost-effective long-term observation system for halocarbons in Europe. (2) To predict and assess impacts of the halocarbons on the climate and on the ozone layer. This implies extensive exploitation of existing data. The impact assessment will be aimed at providing guidance for development of the Kyoto protocol and to the further development of the Montreal protocol mendments, by: - modelling impacts of halocarbons on radiative forcing and their relative importance for climate change; - modelling impacts of emissions of CFCs and HCFCs on the ozone layer.
The aim of QUILT is to optimise the exploitation of the existing European UV-visible monitoring systems by which O3 and the related free radicals NO2, BrO and OClO can be measured. These monitoring systems include ground-based, balloon and satellite observations. QUILT is providing an assessment of the chemical ozone loss over the last decade and through 2000-2003. This is achieved through analysis improvements, consolidation of existing datasets and near real time integrations with chemical transport models.
The goals of this experiment are to map out the chemical changes in the free troposphere as the atmosphere transitions from winter to spring. It is hoped to begin to understand the chemical conditions that influence the lifetime of ozone and understand more about the productivity of this region of the atmosphere with respect to the in-situ production of ozone. How the free troposphere responds to changing levels of pollution could be critical to the development of future abatement strategies.
The overall objective of COSE is to provide the Earth Observation (EO) user community with a validated, consistent and well-documented data set of mainly stratospheric constituent columns and/or profiles, by co-ordination of ground-based observations at existing stations in Europe. The data set builds on past and ongoing time series, and will be archived in a dedicated database for immediate and future exploitation, e.g., satellite validation activities, data assimilation and scientific studies. Active participation of some representative EO customers will assure that the delivered data sets come up to their requirements.
The main specific objectives of UFTIR are: (1) To revise and homogenise the analyses of available experimental data for providing consistent time series of distinct tropospheric and stratospheric abundances of the target gases using new inversion algorithms. A common strategy for retrieval and characterisation of the vertical distributions of the target gases from FTIR ground-based measurements will be established. (2) To provide quantitative trends and associated uncertainties for the target gases over about the last decade, as a function of latitude throughout Western Europe, focusing on the troposphere. (3) To integrate the data in model assessments of the evolutions of tropospheric abundances. The measured burden and changes of the tropospheric gases will be compared with 3D model simulations, in order to help developing the latter, assist in explaining potential causes for the observed changes and to assess the consistencies between the trends at the surface to the free troposphere and lowermost stratosphere, and the agreement with known evolutions of emissions. UFTIR will make the community prepared to deliver tropospheric data for validation and synergistic exploitation of new satellite experiments like ENVISAT.