Canada: projects/activities

In order to assess the spatial and temporal patterns of the a-, b- and g-isomers of hexachlorocyclohexane (HCH) in the arctic biotic and abiotic environment, it is proposed that: (1) concentrations and ratios of HCH isomers be compared over time in air, water, seals, beluga, polar bears and seabirds to determine any shifts in isomeric ratios and how those shifts interrelate among the various media, and (2) concentrations and ratios of HCH isomers be compared spatially in the abiotic and biotic media and reasons for any patterns explored.

The project aims at establishing a long-term Arctic-Antarctic network of monitoring stations for atmospheric monitoring of anthropogenic pollution. Based upon the long and excellent experiences with different scientific groups performing air monitoring within the Arctic Monitoring and Assessment Programme (AMAP), an expanded network will be established including all AMAP stations and all major Antarctic “year-around” research stations. As an integrated project within the “International Polar Year 2007-08” initiative, the ATMOPOL co-operation intend to • Establish a long-term coordinated international Arctic-Antarctic contaminant programme. • Develop and implement a joint sampling and monitoring strategy as an official guideline for all participating stations. • Support bi-polar international atmospheric research with high-quality data on atmospheric long-range transport of contaminants (sources, pathways and fate). • Support future risk assessment of contaminants for Polar Regions based on effects of relevant contamination levels and polar organisms Based upon the well-established experiences of circum-Arctic atmospheric contaminant monitoring in the Arctic under the AMAP umbrella, a bi-polar atmospheric contaminant network will be established and maintained. In conjunction with the polar network of atmospheric monitoring stations for air pollution, surface-based and satellite instrumentation will be utilised to provide the characterization of the Arctic atmospheric-water-ice cycle. Together with numerical weather prediction and chemical transport model calculations, simultaneous measurements of pollutants at various locations in the Arctic and Antarctic will enhance our understanding of chemical transport and distribution as well as their long-term atmospheric trends. In addition to investigating the importance of atmospheric transport of pollutants an understanding of the transference and impact of these pollutants on both terrestrial and marine environments will be sought. A secretariat and a “scientific project board” will be established. During this initial phase of the project (2006), a guideline on priority target compounds, sampling strategies, equipment and instrumentation, analytical requirements, as well as quality assurance protocols (including laboratory intercalibration exercises) will be developed and implemented. The ATMOPOL initiative aims to address highly relevant environmental change processes and, thus, will strive to answering the following scientific questions: • How does climate change influence the atmospheric long-range transport of pollutants? • Are environmental scientists able to fill the gaps in international pollution inventories and identification of possible sources for atmospheric pollution in Polar Regions? • What are the differences in transport pathways and distribution patterns of various atmospheric pollutants between Arctic and Antarctic environments? Why are there such differences? What is the final fate of atmospherically transported pollutants and how does this impact on the environment and indigenous people?In order to understand the underlying atmospheric chemistry of pollution, e.g. atmospheric mercury deposition events, routine surface measurements of UV radiation as well as campaign related measurements of UV radiation profiles will also be included.The project will establish a cooperative network on atmospheric contaminant monitoring in Polar Regions far beyond the IPY 2007/08 period and is, thus, planned as an “open-end” programme. All produced data will be available for all participating institutions for scientific purposes as basis for joint publications and reports from the ATMOPOL database to be developed.

The objectives of the project are: A) to determine temporal trends in atmospheric mercury concentrations and deposition processes of mercury in the Arctic, and to assist in the development of long-term strategies for this priority pollutant by: i) measuring ambient air Total Gaseous Mercury (TGM) concentrations in the Canadian Arctic (Alert) and investigating the linkage to elevated levels of mercury known to be present in the Arctic food chain; ii) investigating and establishing the causes of temporal variability (seasonal, annual) in mercury concentrations so that realistic representations (models) of atmospheric pathways and processes can be formulated, tested and validated; iii) studying the chemical and physical aspects of atmospheric mercury vapour transformation (oxidation) after polar sunrise and the resultant enhanced mercury deposition to the sea, snow and ice surfaces each year during springtime; and iv) obtaining a long-term time series of atmospheric mercury (TGM) concentrations at Alert for the purpose of establishing whether mercury in the troposphere of the northern hemisphere is (still) increasing and if so, at what rate; B) to establish a sound scientific basis for addressing existing gaps of knowledge of the behaviour of mercury in the Arctic environment that will enable international regulatory actions to reflect the appropriate environmental protection strategies and pollution controls for the Arctic by: i) studying the relative roles of anthropogenic and natural sources of mercury so as to clarify understanding of the atmospheric pathways leading to the availability of mercury to Arctic biota; ii) studying tropospheric TGM depletion mechanisms/processes leading to enhanced input of mercury to the Arctic biosphere in spring; iii) undertaking essential speciated measurements of particulate-phase and/or reactive gaseous-phase mercury as well as mercury in precipitation (snow/rain) to quantify wet and dry deposition fluxes into the Arctic environment; and vi) providing the scientific basis for the information and advice used in the preparation and development of Canadian international strategies and negotiating positions for appropriate international control objectives.

The objectives of this project are A) to determine coplanar polychlorinated biphenyls (PCBs), polychlorinated naphthalenes (PCNs), brominated diphenyl ethers (BDPEs), chlorophenolic compounds and chloroparaffins in air from arctic monitoring stations; and B) to search for other "new" chemicals in the arctic environment, not currently monitored by Canada's Northern Contaminants Program (NCP) but of potential concern based on known persistence, extent of usage and toxicology.