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Displaying: 41 - 53 of 53
41. Polybrominated diphenylethers (PBDEs) in the Arctic environment

Polybrominated diphenyl ethers (PBDEs) are persistent and lipophilic compounds used as flame retardants in electronic equipment, plastic material and synthetic fibbers among other things. The PBDEs are mainly used as Deca-BDE and Bromokal 70-5DE, a mixture of tetra-, penta- and hexa-BDE. Due to its chemical and physical properties PBDEs, especially TeBDEs, tend to bioaccumulate. PBDEs were first reported in sediments in USA, and in fish from a Swedish river. More recently PBDEs have also been reported in seals, birds, mussels, whales and humans. In this study an SFE-method for rapid analysis of PBDEs in marine mammals was developed. This method was used to determinate the concentrations of these environmental pollutants in Pilot Whale samples caught in the Faroe Islands, Beluga Whales from the Arctic and Polar Bears from Svalbard. Using this method several PBDEs were analysed in the different species. In addition methoxylated PBDEs (Me-O-PBDE) were identified by interpretation of the different mass spectra’s. Of the 209 theoretical possible congeners only a few PBDE seem to accumulate in the environment. Accumulation of PBDE is related to the different chemical properties of the molecule. With the help of multivariate characterisation of a compound class using semi-empirical molecular orbital calculations, literature data and actual experimental measurements, the behaviour of PBDE in the environment can be modelled and predicted. Such models are essential in order to gain more insight in the behaviour of PBDE in the environment.

SFE extraction Long-range transport Brominated flame retardants Contaminant transport PBDE Supercritical fluid Terrestrial mammals Polybrominated diphenyl ethers Polar bear Persistent organic pollutants (POPs) Sediments Reproduction Marine mammals
42. Endocrine disruption in arctic marine mammals

Assess the effects of POP mixtures present in the food on the endocrine system of marine mammals. Effects of these mixtures on steroid synthesis in adrenals and gonads will be studied in vitro. Further, hormone mimicking effects of contaminant mixtures will be studied. Contaminant receptor binding and responses of the contaminant-receptor complex are studied using estrogen/androgen receptor binding assays in combination with reporte gene assays.

Biological effects Arctic Persistent organic pollutants (POPs) Marine mammals
43. Spatial trends and pathways of POPs and metals in fish, shellfish and marine mammals of northern Labrador and Nunavik

The objectives of this study were to develop baseline data on persistent organic pollutants (POPs) and metals, in freshwater and anadromous fish, shellfish, and marine mammals, important to Inuit communities of Northern Labrador and Nunavik in order to provide the same level of information that is available for other Canadian arctic regions. 1999-00 was the final year of the project. Successful collection of mussels (Mytilus edulis), arctic char (sea run), scallops and walrus samples were made in 1999. During 1998 major collections of ringed seal, sea run arctic char and blube mussels (Mytilus edulis) were made. Chemical analyses of POPs and metals in ringed seals and char collected in 1998-99 were completed in 1999-2000. Low concentrations of mercury, selenium and lead were found in samples of scallops from Labrador while cadmium and arsenic levels were much higher than the other elements, especially in gut samples. Arsenic was the most prominent of the five metals determined in mussels from Nunavik. Mercury levels were low (0.02-0.03 ug/g wet wt) in char from Labrador collected in 1999 similar to our previous observations in Labrador and Nunavik. Much higher levels of mercury and selenium were found in landlocked char (at Kangiqsujuaq) and than in all sea run char from widely separated sites Nunavik and Labrador. Mercury and selenium levels in seal liver did not differ among the 5 locations after adjustment for age of the animals. Percent organic mercury levels increased with age in seal muscle from about 80% in animals from 0-2 yrs to about 100% in adult animals. Mercury levels in walrus meat (muscle) were relatively low compared with liver and kidney. Levels of tributyl tin in char muscle ranged from <0.01 to 0.85 ng/g wet wt and highest levels were found in samples from Kangirsuk (Ungava Bay region). PCBs and other organochlorines were present at very low levels in mussels and arctic char from locations in Nunavik and Labrador. In general, levels of PCBs and SDDT in ringed seal blubber in this study were similar to levels found in ringed seal blubber at other eastern Arctic locations.

mercury Spatial trends arctic char ringed seals
44. Temporal trends of persistent organic pollutants and metals in ringed seals from the Canadian Arctic

The objective of this project is to study long term temporal trends of persistent organic pollutants and mercury in ringed seals from the Canadian arctic. The project rationale is that there are previous results for POPs and mercury in ringed seal tissues for many locations. Furthermore there may be regional differences in temporal trends due to geographical differences in POPs and mercury in marine waters and food webs within the Canadian arctic. It is relatively cost efficient to return to the same locations for additional samples using the same sampling and anlaysis protocols are were used in previous studies (see AMAP and Canadian Assessment Reports). Samples are being collected with the help of hunters and trappers organizations in each community. During 2000-01 samples are being collected at Resolute, Arctic Bay and Pond Inlet. The study will also analyse samples collected recently (1998/99) from Pangnirtung, Arviat and Grise Fiord. Results will be compared with previous data which the Principal Investigator generated in the 1980's and early 1990's. Preliminary results will be available in mid-2001.

Organochlorines PCBs mercury Persistent organic pollutants (POPs) Temporal trends ringed seals Marine mammals
45. Biological core programme

The major aim in AMAP is to monitor the levels of anthropogenic contaminants in all major compartments of the Arctic environment, and assess the environmental conditions in the area. This core programme will provide the Danish/Greenlandic authorities with data which make it possible to take part in the international AMAP programme under the Arctic Council. In order to monitor the levels of anthropogenic pollutants, samples will be collected and analysed. The measured components will include heavy metals and persistent organic pollutants in order to allow for spatial and temporal trends in Arctic biota. The program has taken in consideration the recommended importance of persistent organic pollutants and mercury and the importance of the marine food chain. The core program focuses on areas with high population density or areas with high levels of pollutants in the environment.

Organochlorines PCBs Heavy metals Fish Radioactivity PAHs Spatial trends Environmental management Caribou Terrestrial mammals Arctic Persistent organic pollutants (POPs) Seabirds Reindeer Dioxins/furans Sediments Pesticides Temporal trends Marine mammals
46. Anthropogenic radionuclides in Greenland and the Faroe Islands

It is suggested to analyse a variety of samples from Greenland and the Faroe Islands for radionuclides. The technetium pulse now under way from England will be surveyed in seawater, seaweed and shrimp, and time trends in concentrations of caesium-137, strontium-90 and plutonium will be monitored in selected components of marine, fresh water and terrestrial environments. As far as possible, the sampling programme is coordinated with other sampling programmes in Greenland and the Faroe Islands. It is suggested to re-investigate the weapons plutonium pollution in Bylot Sound off Pituffik on a 5-year basis i.e. year 2002 in the present AMAP programme

technetium marine food plutonium strontium caesium Radionuclides long-distance transport AMAP
47. Contaminants in Greenland Human Diet

Humans in Greenland are exposed to higher intakes of some contaminants from the diet than in most of Europe and North America. The objective of the study is to screen the most important local diet items in West Greenland for cadmium, mercury, selenium and organochlorine contaminants. Mammals, birds, fish and invertebrates, mainly marine species are being analysed.

Organochlorines PCBs Heavy metals Fish Caribou Terrestrial mammals Exposure Persistent organic pollutants (POPs) Seabirds Reindeer Pesticides Diet Human health Human intake Marine mammals
48. Chemical Analysis of Toxaphene, PCB and Chlorinated Pesticides.

The aim of the project is to develop a method for analysis of toxaphene in biota from the marine environment. The project includes a modification/improvement of the method of the chemical analysis of PCBs and cholrinated pesticides used at the Danish Environmental Research Institute.

PCBs Fish Toxaphene Exposure Arctic Persistent organic pollutants (POPs) Seabirds Data management Pesticides Gas Chromatography Negative Ionisation Mass Spectroscopy
49. Quality Assurance of AMAP data

The aim of this project is to conduct quality assurance on the data of organic contaminants obtained in the Greenland / Faroe Islands / Denmark part of the AMAP projects.

Organochlorines PCBs Fish Arctic Persistent organic pollutants (POPs) Seabirds Data management Marine mammals
50. Effects and Trends of POPs on Polar Bears

LONG TERM: Determine the effects, at the individual and population level, of persistent organic pollutants (POPs) and their metabolites in the polar bear; determine trend of POPs in the Arctic marine environment using polar bear tissues as a biomonitor. SHORT TERM: a. Determine 10-year temporal trends of POPs in the Hudson Bay Sub-Arctic Ecosystem from 1990-1989 by analysis of archived polar bear biopsy samples, including changes in enantiomeric composition of -HCH and chlordane compounds and ratio of -HCH/-HCH (cross-referenced to separate proposal on HCHs). b. Determine if there is selective tissue distribution of the enantiomers of chiral contaminants in polar bears, which may influence target organ toxicity, by analysis of archived polar bear samples. c. Determine the endocrine disrupting effect of POPs on testosterone and PCB metabolite profiles by in vitro metabolism studies using polar bear liver microsomes. d. In collaboration with CWS P&N Region, the Norwegian Polar Institute and the Norwegian Veterinary Institute, determine the immunotoxic effects of PCBs and other organochlorines in polar bears throughout a gradient of exposure (Hudson Bay, low; Svalbard, high). e. Determine the effects of hydroxy-PCBs on circulating thyroid hormone and vitamin A concentrations.

Biological effects Organochlorines PCBs Long-range transport Spatial trends Pollution sources Terrestrial mammals Polar bear Exposure Arctic Persistent organic pollutants (POPs) Dioxins/furans Temporal trends Marine mammals
51. New Persistent Chemicals in the Arctic Environment

The objectives of this project are A) to determine coplanar polychlorinated biphenyls (PCBs), polychlorinated naphthalenes (PCNs), brominated diphenyl ethers (BDPEs), chlorophenolic compounds and chloroparaffins in air from arctic monitoring stations; and B) to search for other "new" chemicals in the arctic environment, not currently monitored by Canada's Northern Contaminants Program (NCP) but of potential concern based on known persistence, extent of usage and toxicology.

Sources PCAs BDPEs Pollution sources Exposure monitoring chloroparaffins Sediments Pesticides SCCPs Human intake Marine mammals new chemicals polychlorinated naphthalenes Pathways Organochlorines PCBs chlorinated paraffins Long-range transport brominated diphenyl ethers Spatial trends HAAs Arctic PCNs Persistent organic pollutants (POPs) synthetic musks haloacetic acids Atmosphere polychlorinated alkanes
52. AMAP phase II- Faroe Islands, 2000, core program

The project is meant to cover specific parts of AMAP phase II in the Faroe Islands. The project includes species from the marine and freshwater environment as well as biota from the terrestrial subprogram. The species chosen for the project are to be analysed for the environmental toxins that were termed essential in the guidelines of the circumpolar programme, but minor adjustments may occur. The selection of species to be analysed have been made so as so to elucidate the burden of contaminants in the local and often also traditional food, and at the same time it has been important to ensure comparability between countries in the AMAP area. The biota chosen are pilot whale, black guillemot, hare, sheep and lamb, arctic char and sculpin. In addition to this core program where the above-mentioned are analysed for the limited set of pollutants, certain special tasks have been planned. Examples on such special tasks are the analysis of mercury in sediment core profiles and investigation of the dioxin and POP burden in cows milk.

PCBs Heavy metals Fish Terrestrial mammals Persistent organic pollutants (POPs) Seabirds Pesticides Temporal trends Marine mammals
53. Compiling and summarizing Persistent Organic Pollutant (POPs) data from the U.S. Arctic for the Arctic Monitoring & Assessment Programme (AMAP)

Objectives: 1. Locate and assemble scientific data from the U.S. Arctic on the concentrations and effects of POPs in all compartments (e.g., marine and terrestrial biota, abiotic substrates) of the Arctic. 2. Evaluate, analyze and summarize these scientific data from the U.S. Arctic into text suitable for inclusion in a new (second) AMAP publication on POPs. 3. Disseminate the summarized information via a U.S. AMAP Internet page that is directly linked to the current International AMAP Internet page. Summary (Abstract): The Arctic Monitoring and Assessment Programme (AMAP) was established in 1991 and given the responsibility of monitoring the concentrations and assessing the effects of selected anthropogenic pollutants in all compartments of the Arctic. The first AMAP assessment report, published in 1998, points out gaps in our current understanding of contaminant inputs, their transport processes and food web interactions. In addition, the AMAP report noted a serious lack of information about persistent organic pollutants (POPs) in the U.S. and Russian Arctic. Thus, the recommendations of the first AMAP report were to: monitor spatial distribution, contaminant levels and biological effects of POPs; improve the understanding of the adverse effects of POPs on human populations; and fill existing data gaps, specifically in the U.S. and Russia. In this work, we plan to identify sources of scientific information (e.g., published reports, datasets) on POPs in the U.S. Arctic and obtain these data for AMAP. Once data sources are identified, a small group of scientific experts will be assembled for a workshop to determine if any pertinent sources have been overlooked and to give advice on how best to evaluate, analyze, summarize and disseminate the information obtained. A working database will be designed so that the data and scientifically important findings or conclusions from each study can be organized and evaluated. Data will be analyzed statistically, as appropriate, to determine spatial and temporal trends. The data and scientific findings that have been collected and analyzed will then be summarized into text, for inclusion in the next AMAP publication on POPs. This major effort of synthesizing the existing data from the U.S. Arctic will ensure that the AMAP report adequately presents the accomplishments of U.S. scientists and research programs. The written publication and the summarized U.S. POPs data will also be presented as a U.S. AMAP Internet page linked to the International AMAP Internet page.

Persistent organic pollutants (POPs) SEARCH Data management assessment Phase II