Projects/Activities

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Displaying: 41 - 60 of 112 Next
41. Bioaccumulation, physiological and biochemical effects of pollutants in mussels

In order to evaluate the capacity of mussels to accumulate pollutants and to enhance growth and physiological effects, an investigation was carried out in the Faroe Islands and in the Skagerrak. In March 2000, about 1500 mussels of proper dimensions (length ranging between 5 and 6 cm) were collected in the Kaldbak Fjord (Faroe Islands) on a 10m water column. Selected mussels were divided in 4 groups (320 each) and deployed in 4 different stations (one at the Faroe Islands and three in the Skagerrak). Semipermeable membrane devices (SPMDs) were also deployed in the same stations for the preconcentration of lipophilic pollutants. One month later (end of April-beginning of May) mussels and SPMDs were recollected and sent to different laboratories for the determination of various parameters.

Mytilus Biological effects Biology scope for growth Organochlorines PCBs Heavy metals PCB bioindicator PAHs Long-range transport Contaminant transport Exposure PAH Persistent organic pollutants (POPs) Dioxins/furans SPMD bioconcentration
42. Interactions among infauna, microorganisms and polycyclic aromatic hydrocarbons in marine sediments

Dose-response experiments using 5 different sediment concentrations of fluoranthene (Flu) and pyrene (Py) respectively. Measuring radioactive marked Flu and Py in brittlestars and polychaetes and microbial degradation of Flu and Py in sediment. Also growth rate of brittlestars and polychaetes and determination of regenerationtime of brittlestar-arms.

Biological effects Biology PAHs microorganisms Petroleum hydrocarbons infauna Exposure Sediments
43. Environmental contaminants in Peregrine Falcons in Alaska, USA

Contaminants were examined for trends over time, spatial variation based on disparate breeding areas, and relationships with measures of productivity. Most organochlorines and metals declined over time. Mercury was the only contaminant with possibly increasing concentrations in eggs. Egg and feather samples collected in 2000 will provide more information on mercury trends and effects. This study embodies 20 years of data on environmental contaminants in peregrine falcons nesting in Alaska.

Biological effects Organochlorines PCBs Heavy metals Persistent organic pollutants (POPs) Pesticides Temporal trends
44. Monitoring Beaufort Sea waterfowl and marine birds

The overall project outlined in this proposal represents a series of interrelated studies designed to answer questions regarding the effects of disturbance on distribution and abundance of waterfowl and marine birds. The primary studies (i.e., aerial surveys) are directly related to the objectives identified in the Minerals Management Service (MMS) Statement-of-work regarding Monitoring Beaufort Sea Waterfowl and Marine Birds near the Prudhoe Bay Oil Field, Alaska. Additionally, we plan to include the ‘optional’ studies on eiders using off-shore barrier island habitats. Finally, we propose to conduct ground based studies designed to enhance and expand the interpretation of the aerial surveys. The specific objectives of this study are: 1. Monitor Long-tailed Duck and other species within and among industrial and control areas in a manner that will allow comparison with earlier aerial surveys using Johnson and Gazeys’ (1992) study design. a) Perform replicate aerial surveys of five previously established transects based on existing protocol (OCS-MMS 92-0060). b) Expand the area from original surveys to include near-shore areas along Beaufort Sea coastline between the original “industrial” (Jones-Return Islands) and “control” (Stockton-Maguire-Flaxman Islands) areas. c) Define the range of variation for area waterfowl and marine bird populations. Correlate this variation with environmental factors and oil and gas exploration, development, and production activities. 2. Expand aerial monitoring approximately 50 km offshore. Surveys will target Spectacled, Common and King eiders. The goal is to sample areas potentially impacted by oil spills from the Liberty, Northstar, and/or Sandpiper Units. 3. Develop a monitoring protocol for birds breeding on barrier islands, particularly Common Eiders. These data will be compared to historic data summarized by Schamel (1977) and Moitoret (1998). 4. Examine relationships between life-history parameters (e.g., fidelity, annual survival, productivity) and ranges of variation in Long-tailed Ducks and Common Eider distribution and abundance to enhance interpretation of cross-seasonal effects of disturbance. That is, the combination of aerial and ground based work has the potential to both document changes in abundance/distribution and describe those changes in terms of movements of marked individuals. Parameters will be examined in relation to disturbance using the two-tiered approach developed by Johnson and Gazey (1992). 5. Recommend cost-effective and feasible options for future monitoring programs to evaluate numbers and species of birds potentially impacted by oil spills involving ice-free and ice periods in both inshore and offshore waters.

Biological effects Biology Organochlorines Spatial trends Arctic Persistent organic pollutants (POPs) sea ducks Reproduction Oil and Gas Temporal trends
45. Toxicological effects of bioaccumulated pollutants

Persistent organic pollution is a global problem. This fact is especially apparent in the Arctic where pesticides currently used in distant environments accumulate, in some cases to higher levels than those observed in the source region. This pollution threatens the well-being of the aboriginal inhabitants of these regions. Most of the traditionally harvested animals in the Arctic are long-lived and from the higher trophic levels of the food chain, thereby providing an opportunity for considerable bioaccumulation and biomagnification of persistent contaminants. This has prompted a growing concern by the Alaska Inupiat that pollutants in the environment might be contributing to their unique morbidity and mortality rates, especially of their children. Our studies are currently focused on two specific organic pollutants found in the Arctic environment; 1}hexachlorobenzene (HCB), a byproduct during manufacture of several different chlorinated compounds and consistently detected in the Arctic and, 2} dichlorodiphenyl dichloroethylene (p,p’-DDE), a chlorinated environmental breakdown product measured in the Arctic population at significantly higher concentrations than the parent pesticide, DDT. We hypothesize that mammalian embryonic cell exposure to these chemicals, individually or as mixtures at environmentally relevant concentrations and ratios, will alter the cell cycle and/or cause death by apoptosis, rather than by necrosis. We also predict synergistic cytotoxicity of the chemical mixture because of an accumulation of deleterious effects at different cellular target sites by each chemical. We further hypothesize that while some chemicals target non-genetic cellular components (such as a cell membrane or cytosolic component), other chemical effects will occur primarily at the genetic level, directly or indirectly. Our experiments have been designed as a set of sensitive cellular and molecular assays to compare levels and types of cytotoxic and genotoxic activity of the above chemicals (individual and mixture), at environmentally relevant concentrations, upon embryonic cells in culture. Our experimental evidence thus far is that these chemicals, separately or as a mixture at concentrations and molar ratios relevant to that measured in the Arctic environment, do have cytotoxic and/or genotoxic effects that could result in profound consequences to exposed tissues of a developing embryo or fetus. We have further experimental evidence that exposure to both chemicals at environmentally relevant concentrations is more toxic to the cell than the sum of effects by exposure to the individual chemicals. Experimental results indicate this is due to different cellular target sites for each chemical (Appendix A: Preliminary Results).

Biological effects Indigenous people Exposure Arctic Persistent organic pollutants (POPs) Human health
46. Atmospheric transport modelling of HM/POPs over Europe

The aim of this project is to assess the deposition of HM/POP over Europe and to evaluate models. Within the framework of UN-ECE, EMEP Meteorological Synthesising Centre-East (MSC-E Moscow) organised in co-operation with RIVM, a model intercomparison for operational transport models on HM in 1995. In this intercomparison the RIVM will participate with the TREND-model. Results of the intercomparison will also be reported to the OSPAR commission. A model comparison for POPs will follow later. The RIVM/EUROS model is extended with soil and surface water modules in order to improve the description of the exchange process of POPs (deposition and re-emission). With the model, long-term averages of the deposition and accumulatation of POPs are described and scenario-studies can be carried out. In the first instance, Lindane and B(a)P will be taken as examples of POPs dominantly present respectively in the gas phase and attached to particles. When emissions are available the calculations are extended to other POPs.

Pathways Atmospheric processes Heavy metals PAHs Long-range transport Contaminant transport Modelling Emissions Persistent organic pollutants (POPs) Pesticides Atmosphere
47. 'NAR-2000' expedition

The 'NAR-2000' expedition was performed during August-September 2000. The overall programme of work includes: - monitoring of pollution in air, waters and bottom sediments of freshwater lakes, soils and terrestrial vegetation - soil/botanical studies - visual and remote sensing (aerial photos and video surveys) studies of damage to soil and vegetation cover. Samples of river water and bottom sediments from 25 freshwater bodies and samples from 16 terrestrial sites in the area of the Varandey and Toravey oil fields were taken for chemical analyses.

Biological effects Organochlorines PCBs Soils Catchment studies Heavy metals PAHs Pollution sources phenols Petroleum hydrocarbons Forest damage soil damage Persistent organic pollutants (POPs) Local pollution Sediments Atmosphere Oil and Gas Temporal trends detergents
48. Monitoring pollution of air and precipitation in Arctic Russia

Stationary systematic observations of pollution in atmospheric air and precipitation. During 2000, observations of contaminant levels in atmospheric air in the cities of Murmansk, Nickel, Monchegorsk, Salekhard and Norilsk were conducted. Monitoring of sulphur and nitrogen compounds in air and precipitation was continued at the above locations and also at Yaniskosky (Kola peninsula) and Pinega (Arkhangelsk region) under the EMEP programme framework. Observations of CO2 were continued at the Teriberk station. Observations of the chemical content of atmospheric precipitation were carried out at 5 stations in the Arctic network of stationary observations: in the Krasnoshelye settlement area (Kola peninsula), Naryan-Mar (Pechora river area), Dikson Island, Turuhansk (Yenisey river area), and Kusyur settlement area (Lena river). Under a joint Russian-Canadian-AMAP project, monitoring of POPs and (from 2001) mercury in air at the Amderma site is conducted.

Organochlorines PCBs Arctic haze Heavy metals PAHs Long-range transport Acidification Contaminant transport Persistent organic pollutants (POPs) Local pollution Pesticides Atmosphere EMEP air monitoring urban air quality
49. 'Karex-Pechora' expedition

The 'Karex - Pechora' expedition marine investigations by the research vessel 'Ivan Petrov' in the Kara and Pechora seas in August 2000, and by the research vessel 'Hydrolog' during September-October 2000. During August 2000 samples of marine water, suspended and bottom sediments at 30 oceanographic stations were analyses for contaminants. At 8 stations, hydrobiological investigations included sampling of benthic organisms, plankton and fish, for studies of bioaccumulation and transformation of contaminants.

Shelf seas Organochlorines PCBs Hydrography Heavy metals Fish PAHs Long-range transport Spatial trends Contaminant transport Petroleum hydrocarbons marine benthos Persistent organic pollutants (POPs) Sediments Oil and Gas
50. 'Lena-2000' expedition

The 'Lena-2000' expedition was performed in the area of the mouth of the Lena river and the shelf of the eastern part of the Laptev Sea during August 2000. Samples of river and marine water, suspended and bottom sediments were taken at 30 hydrological stations to study the mechanisms of contaminant transport by river water.

Shelf seas Pathways Organochlorines PCBs Hydrography Catchment studies Heavy metals PAHs Long-range transport Contaminant transport Petroleum hydrocarbons riverine transport Persistent organic pollutants (POPs) Sediments fluxes
51. Expedition of hydrographical vessel 'Nikolai Kolomeets'

The expedition by vessel 'Nikolai Kolomeets'included sampling of marine water, bottom sediments, benthos and plankton for studies of accumulation and transformation of OCs and estimation of related toxic effects on aqueous biocenoses. The marine studies took place during the period July-October 2000 in areas of the Pechora, Kara, Laptev, East-Siberian and Chukchi Seas.

Shelf seas Organochlorines PCBs plankton Long-range transport Contaminant transport marine benthos Oceanography Persistent organic pollutants (POPs) bioaccumulation Sediments
52. 'Arctic-2000' expedition

The expedition 'Arctic-2000' included climatic, hydrometeorological and hydrochemical studies in the eastern part of the Central Arctic Basin, during the period July-August 2000.

Contaminant transport Heavy metals Hydrography Ice Long-range transport Oceanography Organochlorines PAHs PCBs Persistent organic pollutants (POPs) Petroleum hydrocarbons Sea ice
53. Persistent Toxic Substances (PTS), Food Security and Indigenous Peoples of the Russian North

Brief: Assessment of the significance of aquatic food chains as a pathways of exposure of indigenous peoples to PTS, assessment of the relative importance of local and distant sources, and the role of atmospheric and riverine transport of PTS in Northern Russia. Project rationale and objectives: (1) To assess levels of Persistent Toxic Substances (PTS) in the environment in selected areas of the Russian North, their biomagnification in aquatic and terrestrial food chains, and contamination of traditional (country) foods that are important components of the diet of indigenous peoples. (2) To assess exposure of indigenous peoples in the Russian North to PTS, and the human health impacts of pollution from local and remote sources, as a basis for actions to reduce the risks associated with these exposures. (3) To inform indigenous peoples about contamination by PTS of their environment and traditional food sources, and empower them to take appropriate remedial actions to reduce health risks. (4) To enhance the position of the Russian Federation in international negotiations to reduce the use of PTS, and to empower the Russian Association of Indigenous Peoples of the North (RAIPON) to participate actively and fully in these negotiations. Project activities to achieve outcomes: (1) Inventory of local pollution sources in the vicinities of selected indigenous communities. (2) Survey of levels and fluxes of PTS in riverine and coastal marine environment important for indigenous peoples living in these environments and using them for their subsistence; and assessment of fluxes of PTS to these environments via selected rivers and the atmosphere. (3) Dietary surveys of selected indigenous communities. (4) Study of biomagnification, based on measurements of selected PTS in representative species in food chains important for the traditional diet of indigenous populations. (5) Survey and comparative assessment of pollution levels of the indigenous and general population in selected areas. (6) Dissemination of results to all relevant stakeholders.

GEF Catchment studies Contaminant transport Caribou Exposure Reindeer Dioxins/furans Sediments Pesticides persistent toxic substances Human intake Marine mammals Pathways Organochlorines PTS PCBs Soils Heavy metals Fish Indigenous people PAHs Long-range transport Spatial trends Terrestrial mammals Arctic Persistent organic pollutants (POPs) Local pollution Seabirds Food webs Data management Diet Human health
54. Multilateral Cooperative Project on Phase-out of PCB Use, and Management of PCB-contaminated Wastes in the Russian Federation. Phase I - Inventory and Proposals for Priority Remedial Actions

Phase I: Evaluation of the Current Status of the Problem with Respect to Environmental Impact and Development of Proposals for Priority Remedial Actions: The main goal of phase 1 of the multilateral PCB project is the evaluation of the current status of the PCB problem in Russia. The objectives of sub-activities under phase 1 of the project included: - Assessment of the overall production of PCB in the former USSR and Russian Federation, and the calculation of a mass-balance of the amount produced. - Estimation of the total volume of PCB still in use, in equipment and in wastes located within the territories of Russian Federation. - Preparation of an inventory of environmental releases from industrial uses and waste. - Development of proposals for priority remedial actions. Project results are presented in relevant publications (see below).

Sources Organochlorines PCBs Mapping inventory remediation Discharges Pollution sources Environmental management Emissions Persistent organic pollutants (POPs) waste management Data management remedial action Waste
55. Concentrations and patterns of persistent organochlorine contaminants in beluga whale blubber.

White whale (Delphinapterus leucas) blubber samples from three of the five different Alaskan stocks - Cook Inlet (n = 20), Eastern Chukchi Sea (n = 19) and Eastern Beaufort Sea (n = 2) - were analyzed for levels and patterns of chemical contaminants. Blubber of these whales contained sum PCBs, sum DDTs, sum chlordanes, HCB, dieldrin, mirex, *toxaphene and *HCH, generally in concentration ranges similar to those found in white whales from the Canadian Arctic and lower than those in white whales from the highly contaminated St. Lawrence River. The males of the Cook Inlet and Eastern Chukchi Sea stocks had higher mean concentrations of all contaminant groups than did the females of the same stock, a result attributable to the transfer of these organochlorine contaminants (OCs) from the mother to the calf during pregnancy and during lactation following birth. Principal components analysis of patterns of contaminants present in blubber showed that Cook Inlet stock appeared to have identifiable contaminant patterns that allowed the stock to be distinguished from the others. Our results also showed that blubber from the three Alaskan stocks was a source of contaminant exposure for human subsistence consumers, but the health risks from consumption are currently unknown.

Organochlorines white whale PCBs pollutants pollutant burden Arctic monitoring Persistent organic pollutants (POPs) Reproduction Pesticides Human intake Marine mammals
56. Organochlorine contaminants in blubber of Ringed Seals: Integrating biomonitoring and specimen banking

Blubber samples from Alaska ringed seal (Phoca hispida) were collected for inclusion in the US National Biomonitoring Specimen Bank, as well as for immediate analysis as part of the contaminant monitoring component of the US National Marine Fisheries Service's Marine Mammal Health and Stranding Response Program. The blubber samples were analyzed for organochlorine (OC) contaminants (e.g., PCB congeners, pesticides, DDTs). Results for ringed seals from the Alaska Arctic revealed low blubber concentrations of OC contaminants. Differences in contaminant concentrations among the Alaska seals may be explained by differences in feeding habits and migratory patterns; age or gender did not appear to account for the differences observed. The integration of real-time contaminant monitoring with specimen banking provides important baseline data that can be used to plan and manage banking activities. This includes identifying appropriate specimens that are useful in assessing temporal trends and increasing the utility of the banked samples in assessing chemical contaminant accumulation and relationships to biological effects.

Organochlorines PCBs Spatial trends ringed seal Arctic Persistent organic pollutants (POPs) blubber Pesticides Marine mammals
57. Persistent organic pollutants measurements in Arctic fox from the Pribilof Islands, Alaska

Objectives were to measure a suite of organochlorine contaminants in tissues of Arctic fox collected on the Pribilof Islands for comparison to similar measurements in Arctic fox from other locations for the AMAP assessment.

Organochlorines PCBs fat Terrestrial mammals Arctic Persistent organic pollutants (POPs) Pesticides Arctic fox
58. The Bowhead whale as a potential indicator species for monitoring the health of the western Arctic/Bering Sea ecosystem using blubber, histology, metal and mineral indices

I. Objectives: I.1. To determine the normal range of values (natural variability due to time of year, age, gender) for basic nutritional and health parameters (blubber characteristics, essential and non-essential elements, structure of basic tissues) in the bowhead whale. a. Blubber thickness (depth and girth), chemical composition (lipids, water, calories), and tissue structure (light microscopy and special stains) will be assessed. b. Essential and non-essential elements (heavy metals) will be measured in liver and kidney. c. Tissue structure (light microscopy) characteristics obviously related to nutritional status in liver (glycogen, lipid and lipofuscin stores), pancreas (zymogen granules), and intestine (mucosal microvilli) and any evidence of inactivity/atrophy will be examined. d. Documentation of "normal" structure of basic tissues and evaluation for evidence of disease will also be conducted. I.2. Using data from Objective 1 to identify the parameters most important in assaying the health status of other mysticetes residing in the Bering Sea or Western Arctic that are harvested or stranded. I.3. Using data from Objective 1 to help determine the role of the bowhead whale as an indicator of ecosystem health and development of an optimized protocol for assessing mysticete health for the Bering Sea and Western Arctic, and other regions.

Biological effects Biology Organochlorines Heavy metals Arctic Persistent organic pollutants (POPs) Ecosystems Marine mammals
59. Human and chemical ecology of Arctic pathways by marine pollutants

1. Research area # 2 in the 1998/99 Announcement of Opportunity by CIFAR, "Study of anthropogenic influences on the Western Arctic/Bering Sea Ecosystem", and 2. Research area #4 in the 1998/99 Announcement of Opportunity by CIFAR, "Contaminant inputs, fate and effects on the ecosystem" specifically addressing objectives a-c, except "effects." a. "Determine pathways/linkages of contaminant accumulation in species that are consumed by top predators, including humans, and determine sub-regional differences in contaminant levels..." b. "Use an ecosystems approach to determine the effects of contaminants on food web and biomagnification." c. "Encourage local community participation in planning and implementing research strategies." The objectives of Phase I, Human Ecology Research are to: 1. Document reliance by indigenous arctic marine communities in Canada, Alaska and Russia on arctic resources at risk from chemical pollutants; and, 2. Incorporate traditional knowledge systems of subsistence harvesting. The human ecology components of the project were conducted within the frameworks of indigenous environmental knowledge and community participation. Using participatory mapping techniques, semi-structured interviews and the direct participation of community members in research design, data collection and implementation, research and data collection on the human ecology of indigenous arctic marine communities was undertaken in the communities of Holman, NWT (1998), Wainwright, Alaska (1999), and is underway in Novoe Chaplino, Russia. (2000).

Biology Organochlorines PCBs Fish Indigenous people Contaminant transport Stable isotopes Exposure Arctic Persistent organic pollutants (POPs) Food webs Ecosystems Marine mammals
60. Monitoring POPs and heavy metals in the merlin (Falco columbarius)

To monitor levels of pollutants in merlin by analysis of POPs and heavy metals in eggs and feathers. /Feathers and addled eggs of merlin were collected in 1992, 1993, 1994, 1999 and 2000 for chemical analysis of POPs and heavy metals. Comparisons with eggs from museum collections show that there has been a significant shell thinning in eggs of Norwegian merlins. From 1947 up to 1990 the eggs were on average ca. 15% thinner than normal and after 1990 the thinning has been ca. 10%. There are still high concentrations of DDE to reduce reproductive output in some cases. The PCB levels are low compared to the DDE levels and the concentrations of other chlorinated hydrocarbons are also low. Results from mercury analyses indicate possible effects on breeding performance in some adults.

Biological effects Organochlorines PCBs Heavy metals Long-range transport Spatial trends Contaminant transport merlin Persistent organic pollutants (POPs) Food webs Pesticides Temporal trends terrestrial birds